I have published a number of transmitting balun designs, and none of them use enamelled wire. I am sometimes asked why is that so, but more often advised that it is a better solution than the wires that I have used.
enamelled wire depends on an insulating coating, and its breakdown voltage depends on the wire diameter, polymer used, the minimum thickness applied, coating cure / bake processes, temperature, humidity etc.
Whilst I have seen specifications promising breakdown voltage of a single round enamelled wire in the regions of 5-10kV, and you might hope for nearly double that between a pair of twisted wires, unless you have sourced specific product, new performance may be closer to 2kV. Continue reading On use of enamelled wire in transmitting baluns